- Acid when pH<7, has more H3O+
- Base when pH>7, has more OH−
- Neutral when pH=7, has equal amounts
- Acids donate proton, bases receive proton
- Lone pairs make a molecule basic
- Strong acids and bases fully dissociate in H2O
- H2O is amphoteric, can act as acid or base
- Certain reactions are reversible if in equilibrium
Equations
- pH=−log[H3O+], pOH=−log[OH−]
- H3O+=10−pH, OH−=10−pOH
- [H3O+]⋅[OH−]=10−14, pH+pOH=14
Example
- HC2H3O2+H2O⇌H3O++C2H3O2−
| HC2H3O2 | H2O | H3O+ | C2H3O2 |
|---|
| Initial | 1.0 M | Excess | 0 M | 0 M |
| Change | -x M | N/A | +x M | +x M |
| Equilibrium | 1.2 - x M | N/A | x M | x M |
- Ka=1.45⋅10−5=1.2−xx2
- x1=4.1⋅10−3